QUOTE (Aussie @ Jul 19 2007, 07:06 AM)
Dburt,
You make the case that Mars basalt is Fe rich, the planet is exceptionally salty and salty, steamy vapours produce blue-grey hematite flakes as a very common insoluble mineral in terrestrial fumaroles. So when an impact occurs steamy salty surge clouds on Mars should be analogous, and should produce blue-grey hematite nano-scale hematite flakes that would condense and accrete into the spherules. But this scenario requires almost instantaneous oxidisation of the basalt Fe content. Michelle Minitti et al found that it took 3 days at 700 C to oxidise a 0.1 to 0.6 um hematite coating on a mars meteor composition in a CO2 environment.
http://minitti.asu.edu/publications/abstracts/hem_ab.pdf I appreciate that you have argued that the surge cloud will create its own atmosphere, and vapourisation as well as melt is involved, but I still have reservations over the speed at which this process must occur. I find the scenario hard to accept in the absence of any rigorous modelling or terrestrial analogue, and in the light of Minitti’s results. Not impossible, but the sequence of events necessary to form hematite spherules seems far more complex and problematic than the formation of terrestrial impact microkristites.
Also, if this combination of impact energy and martian basalt can produce the spherules, why has this process not occurred in a number of impacts rather than being isolated to a few comparatively small regions? And the regions where grey hematite has been identified (Aram Chaos, and Ophir and Candor Chasma in Valles Marineris ) all have indicators for aqueous activity in the distant past. This seems to point to an aqueous rather than impact cause.
I understand that Geothite can transition to hematite in temperatures as low as 70 C in saturated water vapour given that in an aqueous system, crystal growth effects lower the transition temperature from that required in the dry state. (Catling and Moore Icarus 165 (2003) 277–300). So there is potential that low levels of hydrothermal energy could have created the appropriate conditions for hematite conversion from a goethite spherule precursor in Mars’ early life. A scenario possibly as tenable as impact accretion.
Aussie - Some of these questions have been addressed in previous posts, but bear repeating.
Regarding Michelle Minitti's results - what happens if you roast basalt in a dry CO2 atmosphere is irrelevant - water (or steam) is the great catalyst. Without it, very little happens in the mineral world. Look it up. Also, believe it or not, large impacts heat things to many thousands of degrees - they separate metals from oxygen, at least transiently, and vaporize everything, without exception. Plenty of kinetics, infinitely more interesting than, say, volcanic processes - and equilibrium is hardly expected, with the rapid decompression and cooling. Consider, as a simple example, what might happen to hydrated Mg-sulfate, inferred to be the most common salt at Meridiani. Mg would separate from S and O and H. Then rapidly recombine into MgO, SO2, H2O, and O2 - plenty of oxygen to oxidize iron, and plenty of steam to catalyze the reaction (not to mention salts - why you don't want to buy a used car from a seaside car dealer - too much rust). Iron-containing impact products on Earth, other than the tiny iron condensation spherules found right next to Meteor Crater AZ, are fully oxidized - and the oxygen in the air has little to do with it. It's the oxygen in the target minerals. Also, believe it or not, it's rather difficult to model (or even imagine, for most people) such extremely rapid, disequilibrium processes. So observation of the products may be your best guide.
Regarding "small regions" - that description hardly fits Meridiani.
Also, believe it or not, orbital infrared spectroscopy is an extremely crude tool - at best it detects what's abundant at the surface, and at worst, only thin coatings on something else, or nothing. It utterly failed to detect the 30% sulfate in the Meridiani rocks (even though sulfate vibrational regions are easy for IR in the lab), and was lucky indeed to detect the specular hematite in the spherules. In any region where the hematitic spherules were all small, or less abundant than about 15% (or coated with dust or buried under/mixed with sand or layered rocks), the hematite would probably be invisible to spectrometers in orbit. Ditto if the spherules had a different composition. So far, rovers have landed at only two places on Mars. In both places they have detected spherules (much smaller, less abundant ones at Home Plate), and at both places they have detected what look like salty surge deposits (essentially identical bedding structures, although the MER team seems extremely reluctant to admit this, and papers on one site never mention the other site). Ferric acid sulfates occur at both sites (jarosite is reported from Meridiani, unspecified ones at Gusev). If our impact hypothesis is correct, I might predict that future rovers that land in similar well-bedded rocks should find similar features: surge-type cross-bedding, impact-related spherules, and salts, possibly including acid salts. So far, we're two for two - so feel free to complain about the statistics of small samples.
The "indications of aqueous activity" that you refer to for Aram Chaos, and Ophir and Candor Chasma in Valles Marineris are inferences generally based on the presence of bedding and sulfate salts - also obviously expected for impact deposition (although I'll be the first to admit that water deposition also produces bedding, but the rocks don't look anything like those at Meridiani or Home Plate). BTW, our impact model depends on "aqueous activity" too - but in the form of steam. And we never claimed that the neutral salts don't indicate liquid water - just that that the liquid water could be older than the deposits being observed (see earlier posts). The highly unlikely mixture of soluble and insoluble salts at Meridiani also converted the MER team to this explanation, but they blamed the wind blowing across a long-vanished playa, instead of an impact. Then they wanted to soak the soluble salts many times in brine without recrystallizing them, have water flow briskly across a flat surface, and similar implausibilities.
Regarding "hydrothermal activity" and goethite, that has not been suggested for Meridiani by the MER team recently, so why are you bringing it up? (When the blue-gray or specular hematite IR signature was first detected, a super-giant hot spring system was inferred, but this idea was later quietly laid aside in favor of a giant metamorphosed iron formation, which now has been laid aside in favor of a giant field of sedimentary concretions.) That Catling and Moore (2003) paper is dates from the iron formation hypothesis. Frankly, instead of dealing with the largest hot spring in the solar sytem, or the largest iron formation, or the largest sedimentary concretion field, I find it much easier to blame everything on an ordinary garden-variety impact or impacts, for which there are so many possibilities that it is hard to know where to begin. But that's just me.
--HDP Don