The same thing is true of the UVIS, whose main purpose is obviously to identify the cloud UV absorber. In fact, Esposito proposed a "Venus Composition Probe" for the first Discovery AO (I don't know whether he repeated it) that would have been split into two modules: a vented one just for upper-atmospheric analyses carrying mass and UV spectrometers, and an armored module to survive until impact carrying atmospheric structure sensors and an IR spectrometer to proofile reactive trace gases.
As for Rehling's proposed composition-mapping high-altitude balloons: it might well be possible for them to get acceptable near-IR spectra of the local surface (at least through the limited spectral sunlight windows allowed by Venus' atmosphere and clouds); but it's more open to question as to whether they could get useful images. Tjhere have been quite a few studies of that, reaching differing conclusions:
http://www.sciencedirect.com/science?_ob=A...eb2b26976a8d59f (I ahve Moroz's complete 2002 article, but it's no longer available for free on the Web.)
http://www.lpi.usra.edu/meetings/LPSC98/pdf/1646.pdf
http://www.aas.org/publications/baas/v35n4/dps2003/376.htm
The 1998 one was done in connection with the "VEVA" Discovery proposal for droppable imaging probes ( http://trs-new.jpl.nasa.gov/dspace/bitstre...6/1/00-0365.pdf ), which actually reached quite optimistic conclusions: "Venus’ atmosphere has an opaque cloud deck above ~47-km altitude. Our simulations show that by imaging below the cloud deck in a window in the CO2 absorption at about 1 pm, interpretable images can be obtained even from 47 km altitude (images from this altitude will show primarily surface elevation differences due to the differing optical path lengths to the surface; lower areas will appear brighter). We also simulated the effects of near-isotropic lighting on aerial photographs and found that roughness-induced differences in apparent surface brightness (self-shadowing) provide good contrast between units even under these conditions."